WebCoordination Chemistry Coordination compounds • neutral coordination compounds include the metal and its bound ligands • the number of bonds in a coordination complex does not correlate with the formal oxidation state of the metal • coordination complexes can also be charged –complex cations or complex anions • in a complex ion, the ligands coordinated … WebAbstract The interaction of antitumor drug, cisplatin (cis- [PtCl2 (NH3)2], CDDP) with insulin from porcine pancreas has been investigated by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and high resolution hybrid ion trap/time-of-flight mass spectrometry (MALIDI-TOF/TOF-MS and ESI-IT/TOF MS).
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WebWrite IUPAC name of [PtCl 2(NH 3) 2]. Medium Solution Verified by Toppr Solution:- Oxidation state of NH 3 in the given compound =0 Oxidation state of Cl in the given compound =−1 Let x be the oxidation state of Pt in the given compound. Therefore, x+2(−1)+2(0)=0 ⇒x=+2 Therefore, the IUPAC name of the given coordinate compound is- WebScience Chemistry complexes are optically active? 1- cis- [Co (en) 2 (NH3) 2] + 2- cis- [PtCl2 (NH3) 2] 3- [Cr (ox) 3] 3- 4- trans-diamine-cis-diaqua-cis-dibromochrome (III) ion … login homesearch
Solved The anti-cancer drug known as cisplatin, with Chegg.com
WebThe preparations of cis- and trans-[PtCl2(NH3)2], were discussed on page 74. In all of these, the product is largely the indicated isomer, but reactions frequently produce mixtures of isomers. These can be separated by means of fractional crystallization, ion-exchange chromatography, or other physical techniques. WebThe reaction of cis- [PtCl2 (NH3)2] with intracellular GSH was slower; only 35% of the GSH had been complexed after a 4-hr incubation compared to 70% for the trans isomer. … Web(i) Pt (s) + 2 NH3 (aq) + 2 CI (aq) cis- [PtCl2 (NH3)2] (aq) + 2 e E° = 0.274 V The likely cathodic reaction is the evolution of H₂ gas from water as shown in the equation below. (ii) 2 H₂O (1) +2 e H2 (g) + 2OH (aq) Eº = -0.828 V The given E° values above are at 25 °C. A. login honda panex